Issue 20, 2023

Selective synthesis of two-dimensional semiconductive coordination polymers with silver–sulfur network

Abstract

Two-dimensional Ag(I) coordination polymers containing a sulfur coordination atom, [Ag(tzdt)]n (KGF-24), and [Ag(tzdt)(TFA)]n (KGF-25) (Htzdt = 1,3-thiazolidine-2-thione, TFA = trifluoroacetate), were synthesized and characterized. Time-resolved microwave conductivity measurements and first-principles calculations revealed that KGF-24 and KGF-25 exhibit charge mobility along their (–Ag–S–)n network.

Graphical abstract: Selective synthesis of two-dimensional semiconductive coordination polymers with silver–sulfur network

Supplementary files

Article information

Article type
Communication
Submitted
04 Feb 2023
Accepted
11 Apr 2023
First published
26 Apr 2023

CrystEngComm, 2023,25, 2990-2994

Author version available

Selective synthesis of two-dimensional semiconductive coordination polymers with silver–sulfur network

R. Akiyoshi, A. Saeki, K. Ogasawara, H. Yoshikawa, Y. Nakamura and D. Tanaka, CrystEngComm, 2023, 25, 2990 DOI: 10.1039/D3CE00106G

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