Issue 94, 2023
From the journal:

Chemical Communications

Simply accessible platinum(ii) complexes enabling alkene hydrosilylation at ppm catalyst loadings†

Benon P. Maliszewski, ORCID logo a   Eleonora Casillo,a   Perrine Lambert,a   Fady Nahra, ORCID logo *ab   Catherine S. J. Cazin ORCID logo *a  and  Steven P. Nolan ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S3), Ghent 9000, Belgium
E-mail: steven.nolan@ugent.be

b VITO (Flemish Institute for Technological Research), Separation and Conversion Technology, Boeretang 200, Mol 2400, Belgium
E-mail: fady.nahra@vito.be

Abstract

An efficient olefin hydrosilylation protocol utilising Pt(II)–thioether-based pre-catalysts is reported. These simple and readily available complexes exhibit excellent catalytic performance and offer significant advantages over existing alternatives, enabling rapid and high conversions at ppm-level catalyst loadings.

Graphical abstract: Simply accessible platinum(ii) complexes enabling alkene hydrosilylation at ppm catalyst loadings

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Article information

DOI
https://doi.org/10.1039/D3CC05033E
Article type
Communication
Submitted
12 Oct 2023
Accepted
04 Nov 2023
First published
09 Nov 2023

Chem. Commun., 2023,59, 14017-14020

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Simply accessible platinum(II) complexes enabling alkene hydrosilylation at ppm catalyst loadings

B. P. Maliszewski, E. Casillo, P. Lambert, F. Nahra, C. S. J. Cazin and S. P. Nolan, Chem. Commun., 2023, 59, 14017 DOI: 10.1039/D3CC05033E

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