Issue 28, 2023

Facile preparation of optically active helical polycarbenes with salicylate substituents and their postpolymerization modification

Abstract

Optically active helical polycarbenes were constructed through the living and controlled helix-sense-selective polymerization (HSSP) of methyl salicylate modified diazoacetate monomer catalysed via π-allylPdCl with chiral phosphine ligands. The obtained helical polycarbenes could undergo postpolymerization modification to afford functional polycarbenes efficiently.

Graphical abstract: Facile preparation of optically active helical polycarbenes with salicylate substituents and their postpolymerization modification

Supplementary files

Article information

Article type
Communication
Submitted
16 Jan 2023
Accepted
13 Mar 2023
First published
13 Mar 2023

Chem. Commun., 2023,59, 4201-4204

Facile preparation of optically active helical polycarbenes with salicylate substituents and their postpolymerization modification

H. Zou, S. Tai, S. Zhao, L. Zhou, N. Liu and Z. Wu, Chem. Commun., 2023, 59, 4201 DOI: 10.1039/D3CC00237C

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