Issue 30, 2022, Issue in Progress
From the journal:

RSC Advances

Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes†

Guoqi Zhang, ORCID logo *a   Sihan Li,ab   Haisu Zeng,ab   Shengping Zheng ORCID logo b  and  Michelle C. Neary ORCID logo b  

* Corresponding authors

a Department of Sciences, John Jay College, PhD Program in Chemistry, The Graduate Center, The City University of New York, New York, NY 10019, USA
E-mail: guzhang@jjay.cuny.edu

b Department of Chemistry, Hunter College, The City University of New York, New York, 10065 NY, USA

Abstract

A new diplumbane, namely [Pb(CH2SiMe3)3]2, was synthesized and structurally characterized. This group 14 element compound was found to catalyse the hydroboration of ketones and aldehydes under mild conditions without the use of additives and solvents, leading to the synthesis of a range of alcohols in high yields after hydrolysis.

Graphical abstract: Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes

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Article information

DOI
https://doi.org/10.1039/D2RA03731A
Article type
Paper
Submitted
17 Jun 2022
Accepted
22 Jun 2022
First published
29 Jun 2022
This article is Open Access
Creative Commons BY license

RSC Adv., 2022,12, 19086-19090

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Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes

G. Zhang, S. Li, H. Zeng, S. Zheng and M. C. Neary, RSC Adv., 2022, 12, 19086 DOI: 10.1039/D2RA03731A

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