The formation of value-added cyclic carbonates by the cycloaddition of CO2 to various epoxides is investigated using a ruthenium-based metal–organic framework (Ru-HKUST-1). The Ru-HKUST-1 catalyst demonstrates catalytic activity for CO2 fixation with a high substrate concentration under mild conditions, and is shown to be more active than the traditional Cu-HKUST-1.
J. Ho, M. T. Nord, J. P. Stafford and K. C. Stylianou, Catal. Sci. Technol., 2022, 12, 6998 DOI: 10.1039/D2CY01170K
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