Issue 16, 2022

Organometallic 3d transition metal NHC complexes in oxidation catalysis

Abstract

The development of processes for the selective oxidation of hydrocarbons is a major focus in catalysis research. Making this process simultaneously environmentally friendly is still challenging. 3d transition metals are highly promising candidates to replace expensive and/or toxic heavier metals in their applications as oxidation catalysts. Optimizing such catalytic systems is closely connected to the improvement of stabilizing ligands. In this context, N-heterocyclic carbenes (NHCs) have attracted particular attention. Their strong σ-donor properties, compared to nitrogen or oxygen-donor ligands, allow the stabilisation of transition metals in high oxidation states, known to be key intermediates in oxidation catalysis. This review provides an overview of recent applications of 3d transition metal NHC complexes in oxidation catalysis, by summarising the advances towards the catalytic oxidation of the most important substrates namely alkenes, alkanes, aromatics, alcohols and amines until the end of 2021. Additionally the activation of molecular oxygen, representing a green and abundantly available oxidant, is described with first row transition metal NHC complexes.

Graphical abstract: Organometallic 3d transition metal NHC complexes in oxidation catalysis

Article information

Article type
Perspective
Submitted
19 Jan 2022
Accepted
17 Feb 2022
First published
17 Feb 2022

Catal. Sci. Technol., 2022,12, 4940-4961

Organometallic 3d transition metal NHC complexes in oxidation catalysis

G. G. Zámbó, J. F. Schlagintweit, R. M. Reich and F. E. Kühn, Catal. Sci. Technol., 2022, 12, 4940 DOI: 10.1039/D2CY00127F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements