ZnO nanoparticle confined stress amplified all-fiber piezoelectric nanogenerator for self-powered healthcare monitoring†
Abstract
In this work, an all-fiber piezoelectric nanogenerator (A-PNG) is designed by using ZnO nanoparticles (NPs) reinforced poly(vinylidene fluoride) (PVDF) electrospun nanofibers as the active layer and interlocked conducting microfiber composite mats as electrodes to convert the mechanical energy into electrical power. Theoretical simulation using finite element analysis on stress distribution shows that the external stress can be concentrated to deform ZnO nanoparticles by 7.2 fold of magnitude compared to the surrounding neat PVDF, improving the stress-induced large polarization in the resulting PVDF–ZnO composite nanofibers, thus enabling improved generation of electricity. Nano-scale investigation revealed superior generation of ferro- and piezo-electricity using the PVDF–ZnO composite nanofibers, showing an excellent piezoelectric charge coefficient of d33 = −32 pC N−1. As a result, the A-PNG shows a high electrical throughput, with 18 V of open-circuit output voltage, 26.7 μW cm−2 of output power density, and 11.52 × 10−12 Pa−1 for the piezoelectric figure of merit (FoM). In addition, the excellent mechanical to the electrical energy conversion efficiency of 91%, means that the system is suitable for driving a range of consumer electronics components, such as capacitors and light-emitting diodes (LEDs). The quick response time of 10 ms means it is feasible for ultra-fast signal detection in a healthcare monitoring system. Owing to the skin conformable functionality on different body parts, such as wrists, fingers, throat, and knees, the A-PNG was found to be attractive for application in detecting the pulse rate, muscle behavior, and coughing signal characteristics in order to monitor health conditions. The robust device structure means the A-PNG can be used as a weight monitoring sensor as it is able to predict the weight of a person in a weight range between 45 and 80 kg.
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