Two novel telluroniobates with efficient catalytic activity for the imidation/amidation reaction

Mengyuan Cheng; Yufeng Liu; Nan Li; Jingwen Shi; Weixin Du; Dongdi Zhang; Guoping Yang; Guan Wang; Jingyang Niu

doi:10.1039/D1CC06781H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Two novel telluroniobates with efficient catalytic activity for the imidation/amidation reaction†

Mengyuan Cheng,‡^a Yufeng Liu,‡^b Nan Li,‡^a Jingwen Shi,^a Weixin Du,^a Dongdi Zhang,

*^a Guoping Yang,*^b Guan Wang

^a and Jingyang Niu

*^a

Author affiliations

* Corresponding authors

^a Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, P. R. China
E-mail: ddzhang@henu.edu.cn, jyniu@henu.edu.cn

^b Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, Jiangxi Province Key Laboratory of Synthetic Chemistry, East China University of Technology, Nanchang, P. R. China
E-mail: erick@ecut.edu.cn

Abstract

We present the synthesis and catalytic properties of two novel telluroniobates {Te₁₅Nb₂₁} and {Te₁₀Nb₁₄}. {Te₁₅Nb₂₁} is the first trimeric telluroniobate with the largest number of tellurium atoms in the Te–Nb system. Besides, both clusters exhibit excellent catalytic activity in the amidation reactions of anhydrides and amines, and cyclic imides and bi-amides can be controllably synthesized, which represents a breakthrough in the catalysis of polyoxoniobates.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D1CC06781H
Article type: Communication
Submitted: 02 Dec 2021
Accepted: 16 Dec 2021
First published: 17 Dec 2021

Download Citation

Chem. Commun., 2022,58, 1167-1170

Permissions

Request permissions

Two novel telluroniobates with efficient catalytic activity for the imidation/amidation reaction

M. Cheng, Y. Liu, N. Li, J. Shi, W. Du, D. Zhang, G. Yang, G. Wang and J. Niu, Chem. Commun., 2022, 58, 1167 DOI: 10.1039/D1CC06781H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Two novel telluroniobates with efficient catalytic activity for the imidation/amidation reaction†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Two novel telluroniobates with efficient catalytic activity for the imidation/amidation reaction

Social activity

Search articles by author

Spotlight

Advertisements