Issue 38, 2020

Visible-light-promoted N-centered radical generation for remote heteroaryl migration

Abstract

Herein, an efficient visible-light-mediated N–H heteroarylation via remote heteroaryl ipso-migration has been accomplished. Moderate to good yields were obtained with good functional group tolerance. Moreover, a simple and readily available organic photoredox catalyst was employed, avoiding the use of complex and costly noble metal compounds.

Graphical abstract: Visible-light-promoted N-centered radical generation for remote heteroaryl migration

Supplementary files

Article information

Article type
Paper
Submitted
01 Aug 2020
Accepted
09 Sep 2020
First published
09 Sep 2020

Org. Biomol. Chem., 2020,18, 7663-7670

Visible-light-promoted N-centered radical generation for remote heteroaryl migration

C. Liu, C. Cai, C. Yuan, Q. Jiang, Z. Fang and K. Guo, Org. Biomol. Chem., 2020, 18, 7663 DOI: 10.1039/D0OB01594F

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