From BaAl2(BO3)2O to SnAl2(BO3)2F2: structure transformation based on ion regulation

Ya Wang; Jian Han; Junben Huang; Zhihua Yang; Shuzhao Huang; Shilie Pan

doi:10.1039/D0NJ01544J

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From BaAl₂(BO₃)₂O to SnAl₂(BO₃)₂F₂: structure transformation based on ion regulation†

Ya Wang,‡^ab Jian Han,

‡^ab Junben Huang,

^a Zhihua Yang,

^ab Shuzhao Huang^a and Shilie Pan

*^ab

Author affiliations

* Corresponding authors

^a CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011, China
E-mail: slpan@ms.xjb.ac.cn

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Using BaAl₂(BO₃)₂O as a structural template to explore the Sn–Al–B–O–F system, a new tin(II)-containing aluminum borate fluoride compound, SnAl₂(BO₃)₂F₂, was synthesized successfully using the high-temperature solution method in a closed system. It possesses AlBO₆F₂ units which are interconnected further to form Al–B–O–F channels, and the Sn atoms reside in the related channels. To the best of our knowledge, SnAl₂(BO₃)₂F₂ is the first case with isolated BO₃ groups in tin(II) borates. The UV-vis-NIR diffuse reflectance spectrum indicates that its ultraviolet (UV) cutoff edge is about 240 nm. Furthermore, the first-principles calculations of SnAl₂(BO₃)₂F₂ were carried out.

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Article information

DOI: https://doi.org/10.1039/D0NJ01544J
Article type: Paper
Submitted: 29 Mar 2020
Accepted: 15 May 2020
First published: 15 May 2020

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New J. Chem., 2020,44, 9852-9857

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From BaAl₂(BO₃)₂O to SnAl₂(BO₃)₂F₂: structure transformation based on ion regulation

Y. Wang, J. Han, J. Huang, Z. Yang, S. Huang and S. Pan, New J. Chem., 2020, 44, 9852 DOI: 10.1039/D0NJ01544J

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