Issue 4, 2020
From the journal:

Dalton Transactions

A mixed-ligand strategy regulates thorium-based MOFs†

Zhi-wei Huang, ORCID logo ‡a   Kong-qiu Hu,‡a   Lei Mei,a   Xiang-he Kong,a   Ji-pan Yu,a   Kang Liu,a   Li-wen Zeng,a   Zhi-Fang Chaiab  and  Wei-Qun Shi ORCID logo *a  

* Corresponding authors

a Laboratory of Nuclear Energy Chemistry. Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

b Engineering Laboratory of Advanced Energy Materials, Ningbo Institute of Industrial Technology, Chinese Academy of Sciences, Ningbo, China

Abstract

Two novel thorium-based organic frameworks (Th-IHEP-5 and Th-IHEP-6) were assembled from a hexanuclear thorium cluster, porphyrin derivative ligand and linear carboxylic acid ligands via a mixed-ligand strategy. As a stable heterogeneous catalyst, Th-IHEP-5 exhibited high photocatalytic activity for the oxidation of 2-chloroethyl ethyl sulfide (CEES) and the fixation of CO2. The good catalytic effect is attributed to the large conjugated system of porphyrin and the photosensitizer enhancing effects of bipyridine.

Graphical abstract: A mixed-ligand strategy regulates thorium-based MOFs

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Article information

DOI
https://doi.org/10.1039/C9DT04158C
Article type
Communication
Submitted
25 Oct 2019
Accepted
19 Dec 2019
First published
20 Dec 2019

Dalton Trans., 2020,49, 983-987

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A mixed-ligand strategy regulates thorium-based MOFs

Z. Huang, K. Hu, L. Mei, X. Kong, J. Yu, K. Liu, L. Zeng, Z. Chai and W. Shi, Dalton Trans., 2020, 49, 983 DOI: 10.1039/C9DT04158C

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