Issue 71, 2019
From the journal:

Chemical Communications

Excited-state effects on magnetic properties of U(iii) and U(iv) pyrazolylborate complexes†

Robert F. Higgins, ORCID logo ‡a   Caleb J. Tatebe, ORCID logo b   Suzanne C. Bart ORCID logo b  and  Matthew P. Shores ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA
E-mail: matthew.shores@colostate.edu

b H. C. Brown Laboratory, Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, USA

Abstract

For a family of uranium pyrazolylborate complexes, we observe correlations between excited-state mixing and slow relaxation of magnetization for U(III) complexes, and U⋯B distances in U(IV) complexes.

Graphical abstract: Excited-state effects on magnetic properties of U(iii) and U(iv) pyrazolylborate complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9CC04800F
Article type
Communication
Submitted
22 Jun 2019
Accepted
01 Aug 2019
First published
02 Aug 2019

Chem. Commun., 2019,55, 10611-10614

Author version available


Download author version (PDF)

Permissions

Request permissions

Excited-state effects on magnetic properties of U(III) and U(IV) pyrazolylborate complexes

R. F. Higgins, C. J. Tatebe, S. C. Bart and M. P. Shores, Chem. Commun., 2019, 55, 10611 DOI: 10.1039/C9CC04800F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements