Synthesis of free and ligated 1,2-thiaphosphetanes – expanding the pool of strained P-ligands

Andreas Wolfgang Kyri; Florian Gleim; David Biskup; Gregor Schnakenburg; Arturo Espinosa Ferao; Rainer Streubel

doi:10.1039/C8CC09892A

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Synthesis of free and ligated 1,2-thiaphosphetanes – expanding the pool of strained P-ligands†‡

Andreas Wolfgang Kyri,

^a Florian Gleim,^a David Biskup,^a Gregor Schnakenburg,^a Arturo Espinosa Ferao

*^b and Rainer Streubel

*^a

Author affiliations

* Corresponding authors

^a Institut für Anorganische Chemie, der Rheinischen Friedrich-Wilhelms-Universität Bonn, Gerhardt-Domagk-Straße 1, 53121 Bonn, Germany
E-mail: r.streubel@uni-bonn.de
Web: http://anorganik.chemie.uni-bonn.de/akstreubel/

^b Facultad de Química, Campus de Espinardo, Universidad de Murcia, 30100 Murcia, Spain
E-mail: artuesp@um.es

Abstract

While P(V) 1,2-oxaphosphetanes were investigated in great detail over the past decades, the knowledge about P(V) 1,2-thiaphosphetanes is rather scarce, and P(III) derivatives are unknown. Herein, we present the synthesis of the first P(III) complex derivatives formed in the coordination sphere of group 6 metals and, additionally, the first unligated P(III) 1,2-thiaphosphetanes. The latter display an unusually low HOMO–LUMO gap thus constituting excellent candidates for redox-cycling organocatalysts.

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DOI: https://doi.org/10.1039/C8CC09892A
Article type: Communication
Submitted: 13 Dec 2018
Accepted: 08 Jan 2019
First published: 18 Jan 2019

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Chem. Commun., 2019,55, 1615-1618

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Synthesis of free and ligated 1,2-thiaphosphetanes – expanding the pool of strained P-ligands

A. W. Kyri, F. Gleim, D. Biskup, G. Schnakenburg, A. Espinosa Ferao and R. Streubel, Chem. Commun., 2019, 55, 1615 DOI: 10.1039/C8CC09892A

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Chemical Communications

Synthesis of free and ligated 1,2-thiaphosphetanes – expanding the pool of strained P-ligands†‡

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Synthesis of free and ligated 1,2-thiaphosphetanes – expanding the pool of strained P-ligands

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