SCHEDULED MAINTENANCE
Total synthesis of conosilane A via a site-selective C–H functionalization strategy†
Xingang
Xie, 
a
Xuegong
She
*ab
a
Xuegong
She
*ab
Abstract
The first total synthesis of conosilane A, a densely oxygenated nonisoprenoid sesquiterpene, has been achieved through stereoselective intramolecular radical cyclization and double utilization of site-selective C–H functionalization as key steps, thus simplifying the synthetic endeavors in natural product synthesis.
- This article is part of the themed collection: Natural product synthesis
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