Chemoselective Dieckmann cyclisation reactions on N-malonyl thiazolidine templates derived from cysteine and pivaldehyde or aromatic aldehydes may be used to access bicyclic tetramates, for which different pathways operate as a result of differing ring-chain tautomeric behaviour of the respective intermediate imines.
T. D. Panduwawala, S. Iqbal, R. Tirfoin and M. G. Moloney, Org. Biomol. Chem., 2016, 14, 4464 DOI: 10.1039/C6OB00557H
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