Issue 30, 2016
From the journal:

Dalton Transactions

Fischer–Tropsch synthesis over MOF-supported cobalt catalysts (Co@MIL-53(Al))

V. I. Isaeva,*a   O. L. Eliseev,a   R. V. Kazantsev,a   V. V. Chernyshev,bd   P. E. Davydov,a   B. R. Saifutdinov,c   A. L. Lapidusa  and  L. M. Kustovab  

* Corresponding authors

a N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prospect 47, Moscow 119991, Russia
E-mail: sharf@ioc.ac.ru
Fax: +74991372935
Tel: +74991372935

b Chemistry Department, M.V. Lomonosov Moscow State University, Leninskie Gory 1, bldg. 3, Moscow 119992, Russia

c Samara State Technical University, Molodogvardeiskaya ul. 244, Samara 443100, Russia

d A. N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS, 31 Leninsky prospect, Moscow 119071, Russia

Abstract

Novel nanohybrid materials were prepared by immobilizing Co nanoparticles on a microporous framework MIL-53(Al) as a porous host matrix. The synthesized cobalt-containing materials were characterized by XRD, STEM, and oxygen titration. The catalytic performance of Co@MIL-53(Al) nanohybrids was examined in Fischer–Tropsch synthesis (FTS) for the first time. A higher selectivity to C5+ hydrocarbons and lower selectivity to methane for Co@MIL-53(Al) as compared to conventional Co/Al2O3 were observed.

Graphical abstract: Fischer–Tropsch synthesis over MOF-supported cobalt catalysts (Co@MIL-53(Al))

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Article information

DOI
https://doi.org/10.1039/C6DT01394E
Article type
Paper
Submitted
11 Apr 2016
Accepted
29 Jun 2016
First published
29 Jun 2016

Dalton Trans., 2016,45, 12006-12014

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Fischer–Tropsch synthesis over MOF-supported cobalt catalysts (Co@MIL-53(Al))

V. I. Isaeva, O. L. Eliseev, R. V. Kazantsev, V. V. Chernyshev, P. E. Davydov, B. R. Saifutdinov, A. L. Lapidus and L. M. Kustov, Dalton Trans., 2016, 45, 12006 DOI: 10.1039/C6DT01394E

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