Initial-stage oriented-attachment one-dimensional assembly of nanocrystals: fundamental insight with a collision–recrystallization model

Yu Pan; Weiqiang Lv; Yinghua Niu; Kechun Wen; Xiaorong Hou; Jianmin Gu; Minda Zou; Luhan Ye; Wei Wang; Kelvin H. L. Zhang; Weidong He

doi:10.1039/C5RA08796A

Initial-stage oriented-attachment one-dimensional assembly of nanocrystals: fundamental insight with a collision–recrystallization model†

Yu Pan,‡^a Weiqiang Lv,‡^a Yinghua Niu,^a Kechun Wen,^a Xiaorong Hou,^a Jianmin Gu,^a Minda Zou,^a Luhan Ye,^a Wei Wang,^b Kelvin H. L. Zhang*^c and Weidong He*^ade

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* Corresponding authors

^a School of Energy Science and Engineering, University of Electronic Science and Technology of China (UESTC), Chengdu 611731, PR China
E-mail: weidong.he@uestc.edu.cn, weidong.he@vanderbilt.edu

^b School of Materials Science and Engineering, Shenzhen Graduate School, Harbin Institute Technology, Shenzhen 518055, PR China

^c Department of Materials Science & Metallurgy, University of Cambridge, 27 Charles Babbage Road, Cambridge, UK CB3 0FS
E-mail: hz256@cam.ac.uk

^d Interdisciplinary Program in Materials Science, Vanderbilt University, Nashville, Tennessee 37234-0106, USA

^e Vanderbilt Institute of Nanoscale Science and Engineering, Vanderbilt University, Nashville, Tennessee 37234-0106, USA

Abstract

Oriented attachment (OA) growth has been a promising method for the synthesis of one dimensional (1D) anisotropic nanocrystals (NCs). An unresolved fundamental issue is to understand the growth mechanism at the initial stage of an OA nanorod (NR) growth. In this report, a collision–recrystallization model is proposed to investigate the initial OA growth of NRs. The repulsive electrical double layer (EDL) interaction and the attractive van der Waals (vdW) interaction at the initial OA stage are derived by the accurate surface element integration (SEI) technique and the classical Hamaker equation, respectively. Our results show that the self-recrystallization of nanochains increases the collision activation energy of NPs dramatically as their surface potentials and Hamaker constants increase. Under a specific electrolyte concentration, the collision activation energy reaches the maximum, indicating that the growth rate of OA can be controlled by adjusting the electrolyte concentration.

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Initial-stage oriented-attachment one-dimensional assembly of nanocrystals: fundamental insight with a collision–recrystallization model†

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