Issue 56, 2015
From the journal:

Chemical Communications

Copper-catalyzed aerobic conversion of the C[double bond, length as m-dash]O bond of ketones to a C[triple bond, length as m-dash]N bond using ammonium salts as the nitrogen source†

Bin Xu,a   Qing Jiang,a   An Zhao,a   Jing Jia,a   Qiang Liu,a   Weiping Luoa  and  Cancheng Guo*a  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China
E-mail: ccguo@hnu.edu.cn
Fax: +86-731-88821488
Tel: +86-731-88821488

Abstract

The conversion of the C[double bond, length as m-dash]O bond of ketones to a C[triple bond, length as m-dash]N bond is described. This conversion is catalyzed by copper salts with ammonium salts as the nitrogen source in the presence of molecular oxygen. A wide variety of ketones can be converted into the corresponding compounds containing a C[triple bond, length as m-dash]N bond. Based on the preliminary experiments, a plausible mechanism of this transformation is disclosed.

Graphical abstract: Copper-catalyzed aerobic conversion of the C [[double bond, length as m-dash]] O bond of ketones to a C [[triple bond, length as m-dash]] N bond using ammonium salts as the nitrogen source

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5CC02578H
Article type
Communication
Submitted
29 Mar 2015
Accepted
03 Jun 2015
First published
04 Jun 2015

Chem. Commun., 2015,51, 11264-11267

Author version available

Download author version (PDF)

Permissions

Request permissions

Copper-catalyzed aerobic conversion of the C[double bond, length as m-dash]O bond of ketones to a C[triple bond, length as m-dash]N bond using ammonium salts as the nitrogen source

B. Xu, Q. Jiang, A. Zhao, J. Jia, Q. Liu, W. Luo and C. Guo, Chem. Commun., 2015, 51, 11264 DOI: 10.1039/C5CC02578H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements