Issue 48, 2015
From the journal:

Chemical Communications

Radical polymerization of 2,3-dimethyl-1,3-butadiene in coordination nanochannels†

Takashi Uemura,*ab   Ryo Nakanishi,a   Shuto Mochizuki,a   Yasujiro Muratac  and  Susumu Kitagawa*ad  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: uemura@sbchem.kyoto-u.ac.jp

b CREST, Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

c Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan

d Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: kitagawa@icems.kyoto-u.ac.jp

Abstract

Radical polymerization of unpolymerizable sterically hindered butadiene was successfully performed in the nanochannels of porous coordination polymers because of the effective suppression of unfavourable termination reactions. Microstructures of the resulting polymer could also be tuned depending on the structure of the porous hosts.

Graphical abstract: Radical polymerization of 2,3-dimethyl-1,3-butadiene in coordination nanochannels

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Article information

DOI
https://doi.org/10.1039/C5CC01933H
Article type
Communication
Submitted
07 Mar 2015
Accepted
07 May 2015
First published
08 May 2015

Chem. Commun., 2015,51, 9892-9895

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Radical polymerization of 2,3-dimethyl-1,3-butadiene in coordination nanochannels

T. Uemura, R. Nakanishi, S. Mochizuki, Y. Murata and S. Kitagawa, Chem. Commun., 2015, 51, 9892 DOI: 10.1039/C5CC01933H

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