Issue 43, 2013
From the journal:

RSC Advances

Nanocrystalline zinc peroxide mediated unprecedented nitrene transfer: an expeditious access to N-tosylaziridines†

Sanny Vermaa  and  Suman L. Jain*a  

* Corresponding authors

a Chemical Sciences Division, CSIR-Indian Institute of Petroleum, Dehradun-248005, India
E-mail: suman@iip.res.in
Fax: +91-135-2660202
Tel: +91-135-2525788

Abstract

An unprecedented zinc peroxide (ZnO2) assisted synthetic strategy is reported for the synthesis of N-tosylaziridines from alkenes by using N-tosyliminotriphenylphosphorane (Ph3P[double bond, length as m-dash]NTs) as a nitrene transfer reagent under mild reaction conditions. The reaction of zinc peroxide with Ph3P[double bond, length as m-dash]NTs yielded a zinc oxaziridine intermediate which subsequently reacts with alkenes to give corresponding N-tosylaziridines in high to excellent yields.

Graphical abstract: Nanocrystalline zinc peroxide mediated unprecedented nitrene transfer: an expeditious access to N-tosylaziridines

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Article information

DOI
https://doi.org/10.1039/C3RA43878C
Article type
Communication
Submitted
25 Jul 2013
Accepted
15 Aug 2013
First published
21 Aug 2013

RSC Adv., 2013,3, 19830-19833

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Nanocrystalline zinc peroxide mediated unprecedented nitrene transfer: an expeditious access to N-tosylaziridines

S. Verma and S. L. Jain, RSC Adv., 2013, 3, 19830 DOI: 10.1039/C3RA43878C

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