Issue 10, 2013

Cobalt carbonyl as an effective CO source in one-pot synthesis of esters from aryl halides

Abstract

For the first time, we have successfully applied Co2(CO)8 as an effective carbonyl source for the Pd catalysed alkoxycarbonylation of aryl halides affording the corresponding aryl esters under mild microwave conditions. A wide variety of esters and carbonyl derivatives were prepared using this protocol.

Graphical abstract: Cobalt carbonyl as an effective CO source in one-pot synthesis of esters from aryl halides

Supplementary files

Article information

Article type
Paper
Submitted
22 May 2013
Accepted
05 Jul 2013
First published
02 Aug 2013

New J. Chem., 2013,37, 3050-3056

Cobalt carbonyl as an effective CO source in one-pot synthesis of esters from aryl halides

P. Baburajan, R. Senthilkumaran and K. P. Elango, New J. Chem., 2013, 37, 3050 DOI: 10.1039/C3NJ00548H

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