Issue 36, 2013

An iron(iii) tetradentate monoamido complex as a nonheme iron-based peroxidase mimetic

Abstract

A mononuclear iron(III) complex of a noncyclic tetradentate monoamido ligand, Fe(III)mpaq, catalyses the oxidation of Orange II, guaiacol, ABTS and Amplex Red with H2O2 in aqueous solutions at neutral pH. Under identical conditions, other structurally related nonheme iron complexes showed only negligible activities.

Graphical abstract: An iron(iii) tetradentate monoamido complex as a nonheme iron-based peroxidase mimetic

Supplementary files

Article information

Article type
Communication
Submitted
04 Jun 2013
Accepted
20 Jul 2013
First published
23 Jul 2013

Dalton Trans., 2013,42, 12878-12882

An iron(III) tetradentate monoamido complex as a nonheme iron-based peroxidase mimetic

Y. Hitomi, K. Hiramatsu, K. Arakawa, T. Takeyasu, M. Hata and M. Kodera, Dalton Trans., 2013, 42, 12878 DOI: 10.1039/C3DT51483H

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