Issue 67, 2013
From the journal:

Chemical Communications

[CoI(CN)2(CO)3]−, a new discovery from an 80-year-old reaction†

Wenfeng Lo,a   Chunhua Hu,*b   Marck Lumeij,c   Richard Dronskowski,c   Michael Lovihayeem,a   Oren Ishala  and  Jianfeng Jiang*a  

* Corresponding authors

a Department of Chemistry, Yeshiva University, 2495 Amsterdam Avenue, New York, NY 10033, USA
E-mail: jiang@yu.edu
Fax: +1 212-9600035
Tel: +1 212-9605400 ext. 5225

b Department of Chemistry, New York University, 100 Washington Square East, New York, NY 10003, USA
E-mail: chunhua.hu@nyu.edu
Fax: +1 212-9954895
Tel: +1 212-9988769

c Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, D-52056 Aachen, Germany

Abstract

A systematic study of the 80-year-old simple and fundamental reaction of cobalt(II) salt with cyanide under one atmosphere CO was carried out and two novel Co(I) complexes were isolated in the absence of hydroxide. These complexes are the first structurally characterized mixed cobalt CO–CN− compounds.

Graphical abstract: [CoI(CN)2(CO)3]−, a new discovery from an 80-year-old reaction

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Article information

DOI
https://doi.org/10.1039/C3CC43269F
Article type
Communication
Submitted
02 May 2013
Accepted
22 May 2013
First published
22 May 2013

Chem. Commun., 2013,49, 7382-7384

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[CoI(CN)2(CO)3]−, a new discovery from an 80-year-old reaction

W. Lo, C. Hu, M. Lumeij, R. Dronskowski, M. Lovihayeem, O. Ishal and J. Jiang, Chem. Commun., 2013, 49, 7382 DOI: 10.1039/C3CC43269F

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