Issue 20, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

New homoleptic metal carbonyl cations: the syntheses, vibrational and 13C MAS NMR spectra of hexacarbonyl-ruthenium(II) and-osmium(II) undecafluorodiantimonate(V), [Ru(CO)6][Sb2F11]2 and [Os(CO)6][Sb2F11]2

Changqing Wang,   Bianca Bley,   Gerd Balzer-Jöllenbeck,   Andrew R. Lewis,   Sun C. Siu,   Helge Willner  and  Friedhelm Aubke  

Abstract

The new homoleptic carbonyl cations [Ru(CO)6]2+ and [Os(CO)6]2+ are obtained as [Sb2F11]– salts by the reductive carbonylation of M(SO3F)3(M = Ru, Os), under very mild conditions (60–90 °C, 1 atm CO), in liquid SbF5 in a simple, one-step procedure, and are characterized by FT Raman, FTIR and 13C MAS NMR spectroscopy.

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Article information

DOI
https://doi.org/10.1039/C39950002071
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 2071-2072

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New homoleptic metal carbonyl cations: the syntheses, vibrational and 13C MAS NMR spectra of hexacarbonyl-ruthenium(II) and-osmium(II) undecafluorodiantimonate(V), [Ru(CO)6][Sb2F11]2 and [Os(CO)6][Sb2F11]2

C. Wang, B. Bley, G. Balzer-Jöllenbeck, A. R. Lewis, S. C. Siu, H. Willner and F. Aubke, J. Chem. Soc., Chem. Commun., 1995, 2071 DOI: 10.1039/C39950002071

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