Issue 7, 1995

N-(3,4-dihydro-4-oxoquinazolin-3-yl)pyridmium imides: aziridinating agents for alkenes: measurement of rotational barriers around each N–N bond in an N–N–N system

Abstract

Pyridinium imides 35 and 8 are obtained as crystalline solids from the reaction of 3-acetoxyaminoquinazolinones 2 and 10 with the corresponding pyridines; barriers to rotation around each of the N–N bonds in 3 have been measured by NMR spectroscopy, and the imides 35 react both with styrene and with diethyl fumarate to give the corresponding aziridines.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 727-728

N-(3,4-dihydro-4-oxoquinazolin-3-yl)pyridmium imides: aziridinating agents for alkenes: measurement of rotational barriers around each N–N bond in an N–N–N system

R. S. Atkinson, E. Barker, P. J. Edwards and G. A. Thomson, J. Chem. Soc., Chem. Commun., 1995, 727 DOI: 10.1039/C39950000727

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