Issue 23, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Catalytic conversions in water: a novel carbonylation reaction catalysed by palladium trisulfonated triphenylphosphine complexes

Georgios Papadogianakis,   Leendert Maat  and  Roger A. Sheldon  

Abstract

The renewable basic chemical 5-hydroxymethylfurfural (HMF) is selectively carbonylated to the new compound 5-formylfuran-2-acetic acid using a water-soluble palladium complex of trisulfonated triphenylphosphine as the catalyst in an acidic aqueous medium at 70 °C and 5 bar CO pressure; when hydrogen iodide is the acid component, the reaction follows a different course and HMF is selectively reduced to 5-methylfurfural.

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Article information

DOI
https://doi.org/10.1039/C39940002659
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2659-2660

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Catalytic conversions in water: a novel carbonylation reaction catalysed by palladium trisulfonated triphenylphosphine complexes

G. Papadogianakis, L. Maat and R. A. Sheldon, J. Chem. Soc., Chem. Commun., 1994, 2659 DOI: 10.1039/C39940002659

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