SCHEDULED MAINTENANCE
This study reports a three-step synthesis of 3-halomethyl-2,3,4,5-tetrahydro-2,5-methano-1 H-2-benzazepines 2a–c and the rearrangement of 2a–b to 4-iodo- and 4-bromo-1,2,3,4,5,6-hexahydro-2,6-methano-2-methano-2-benzazocines 1a–b.
B. E. Blough, S. W. Mascarella, R. B. Rothman and F. I. Carroll, J. Chem. Soc., Chem. Commun., 1993, 758 DOI: 10.1039/C39930000758
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