Issue 20, 1992

Assembly of heterometallic V2M2S4 cubane-like clusters. Syntheses and structures of [Et4N]2[V2M2S4(OC4H8dtc)2(SPh)2](M = Cu, Ag; dtc = dithiocarbamate)

Abstract

Two V2M2S4 cubane-like cluster dianions (M = Cu, Ag) in which each distorted square pyramidal vanadium atom is chelated by a O(CH2CH2)2NCS2 group (OC4H8dtc)(dtc = dithiocarbamate) and each four-coordinate M atom linked by a terminal PhS group are prepared from an assembly system including VS43–, CuCl [or Ag(PPh3)2+], OC4H8dtc and PhS and are structurally characterized.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1512-1514

Assembly of heterometallic V2M2S4 cubane-like clusters. Syntheses and structures of [Et4N]2[V2M2S4(OC4H8dtc)2(SPh)2](M = Cu, Ag; dtc = dithiocarbamate)

Y. Yang, Q. Liu, L. Huang, B. Kang and J. Lu, J. Chem. Soc., Chem. Commun., 1992, 1512 DOI: 10.1039/C39920001512

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