Alkenes, alcohols, a sulfide, a sulfoxide and diphenylacetylene can be hetero-cooxygenated with PPh3 catalysed by a dicobalt complex: [Co2(µ-OH)L]{H3L = 2,6-bis[(2-hydroxyphenyl)iminomethyl]-4-methylphenol}, to produce a single oxidation product for each substrate.
Y. H. Hwang and C. P. Cheng, J. Chem. Soc., Chem. Commun., 1992, 317 DOI: 10.1039/C39920000317
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