Issue 2, 1989

A bent mixed-valence manganese(III/II/III) complex: a new class of trinuclear, acetate bridged Schiff's base compounds exhibiting a g= 2 multiline e.s.r. signal

Abstract

The e.s.r. spectrum of the bent mixed valence Mn(III/II/III)(saladhp)2(OAc)4(MeOH)2[saladhp = 2-(salicylideneaminato)- 1,3-dihydroxy-2-methylpropane] in dimethylformamide provides the observation of a multiline e.s.r. signal from a trinuclear mixed-valence manganese complex and allows for the comparison of magnetic and spectroscopic properties of related models for the photosynthetic water oxidizing enzyme.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 84-86

A bent mixed-valence manganese(III/II/III) complex: a new class of trinuclear, acetate bridged Schiff's base compounds exhibiting a g= 2 multiline e.s.r. signal

D. P. Kessissoglou, M. L. Kirk, C. A. Bender, M. S. Lah and V. L. Pecoraro, J. Chem. Soc., Chem. Commun., 1989, 84 DOI: 10.1039/C39890000084

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements