Issue 12, 1988

Evidence for enhancement of catalysis by a second metal in heterobinuclear complexes: X-ray structure of [H(CO)(PPh3)2Ru(bim)Rh(cod)](bim = 2,2′-bi-imidazolato, cod = cyclo-octa-1,5-diene)

Abstract

The binuclear complexes [H(CO)(PPh3)2Ru(bim)M(cod)](M = Rh or Ir, cod = cyclo-octa-1,5-diene) are more active as catalysts for the reduction of cyclohexanone, styrene, benzylideneacetophenone, and cyclohexene than the mononuclear parent (ruthenium, rhodium, or iridium) compounds.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 793-795

Evidence for enhancement of catalysis by a second metal in heterobinuclear complexes: X-ray structure of [H(CO)(PPh3)2Ru(bim)Rh(cod)](bim = 2,2′-bi-imidazolato, cod = cyclo-octa-1,5-diene)

M. P. García, A. M. López, M. A. Esteruelas, F. J. Lahoz and L. A. Oro, J. Chem. Soc., Chem. Commun., 1988, 793 DOI: 10.1039/C39880000793

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