Issue 23, 1987

Stereospecificity in radical carbon–carbon bond formation reactions based on tartaric acid

Abstract

Radical decarboxylative addition to activated alkenes, using the thiohydroxamic ester method, of a suitably protected derivative of (+)-L-tartaric acid leads to overall substitution of the carboxy group with essentially complete retention of configuration.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1790-1792

Stereospecificity in radical carbon–carbon bond formation reactions based on tartaric acid

D. H. R. Barton, A. Gateau-Olesker, S. D. Gero, B. Lacher, C. Tachdjian and S. Z. Zard, J. Chem. Soc., Chem. Commun., 1987, 1790 DOI: 10.1039/C39870001790

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