Issue 14, 1987

The first heptaruthenium cluster: X-ray crystal structure of Ru7(CO)184-PPh)2, a molecule consisting of fused square pyramidal polyhedra

Abstract

The first heptaruthenium cluster Ru7(CO)184-PPh)2 has been obtained from the pyrolysis of the phosphido complex (µ-H)Ru3(CO)10(µ-PPh2) in toluene; X-ray analysis has revealed a novel condensed metal framework based on two square pyramidal Ru5 fragments sharing a common face.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1049-1050

The first heptaruthenium cluster: X-ray crystal structure of Ru7(CO)184-PPh)2, a molecule consisting of fused square pyramidal polyhedra

F. Van Gastel, N. J. Taylor and A. J. Carty, J. Chem. Soc., Chem. Commun., 1987, 1049 DOI: 10.1039/C39870001049

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