Issue 24, 1985

Studies of polyketide chain-assembly processes: origins of the hydrogen and oxygen atoms in colletodiol

Abstract

The Origins of all the oxygen and hydrogen atoms in colletodiol (2) have been elucidated by incorporation of label from [1-13C,18O2]- and [1-13C,2H3]-acetate and 18O2 gas into (2) in clusters of Cytospora sp.(ATCC 20502); from the resultant labelling pattern the structures of the enzyme-bound precursors can be deduced and information obtained on the processes occurring during the early stages of polyketide chain-assembly.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1822-1824

Studies of polyketide chain-assembly processes: origins of the hydrogen and oxygen atoms in colletodiol

T. J. Simpson and G. I. Stevenson, J. Chem. Soc., Chem. Commun., 1985, 1822 DOI: 10.1039/C39850001822

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