Issue 8, 1985

Intramolecular interactions in bis(pentamethylcyclopentadienyl) complexes: X-ray structures of (η5-C5Me5)2Zr(OH)(Cl) and (η5-C5Me5)2Zr(OH)2

Abstract

The structure of (η5-C5Me5)2Zr(OH)(Cl)(1) and (η5-C5Me5)2Zr(OH)2(2) have been determined by X-ray diffraction; location of all hydrogen atoms in (1) has established the presence of significant intramolecular non-bonding contacts and (2) is the first early transition metal dihydroxo complex to be structurally characterized.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 456-458

Intramolecular interactions in bis(pentamethylcyclopentadienyl) complexes: X-ray structures of (η5-C5Me5)2Zr(OH)(Cl) and (η5-C5Me5)2Zr(OH)2

R. Bortolin, V. Patel, I. Munday, N. J. Taylor and A. J. Carty, J. Chem. Soc., Chem. Commun., 1985, 456 DOI: 10.1039/C39850000456

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