Enantioselective reductions of prochiral aromatic ketones with adducts formed between ammonia-borane and (2R,3R,11R,12R)- and (2S,3S,11S,12S)-tetraphenyl-1,4,7,10,13,16-hexaoxacyclo-octadecane, (RRRR)-(3) and (SSSS)-(3), have afforded the corresponding (S) and (R) aromatic secondary alcohols with enantiomeric excesses of 20–67%.
B. L. Allwood, H. Shahriari-Zavareh, J. F. Stoddart and D. J. Williams, J. Chem. Soc., Chem. Commun., 1984, 1461 DOI: 10.1039/C39840001461
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