Bis(pentamethylcyclopentadienyl)lutetium complexes Lu(η5-C5Me5)2R (R = Me, H) react at 20–50 °C in hydrocarbon solvents with benzene, pyridine, the ylide CH2PPh3, and tetramethylsilane to give stable, isolatable products of C–H activation, i.e. metallation at a carbon of the reagent with extrusion of R–H.
P. L. Watson, J. Chem. Soc., Chem. Commun., 1983, 276 DOI: 10.1039/C39830000276
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