SCHEDULED MAINTENANCE
Alkyl phenyl sulphides are converted with sulphuryl chloride and pyridine under controlled temperatures into 1,1-dichloroalkyl phenyl sulphides or 1-chloroalk-1-enyl sulphides; treatment of these intermediates with methanol-water (1%v/v) and mercury(II) acetate–formic acid gives, respectively, methyl carboxylic esters and carboxylic acids.
C. C. Fortes, H. C. Fortes and D. C. R. G. Gonçalves, J. Chem. Soc., Chem. Commun., 1982, 857 DOI: 10.1039/C39820000857
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