Pentaphenylbismuth is a useful reagent for the specific ortho-phenylation of phenols under very mild conditions, a comparison of this reagent with triphenylbismuth carbonate being drawn; arylation reactions of the carbonate have been extended to include nitro-compounds and amides.
D. H. R. Barton, J. Blazejewski, B. Charpiot, D. J. Lester, W. B. Motherwell and M. T. B. Papoula, J. Chem. Soc., Chem. Commun., 1980, 827 DOI: 10.1039/C39800000827
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