Issue 12, 1979

Diels–Alder reaction of furan and fumaryl chloride: X-ray crystal and molecular structure of an oxabicyclo[2.2.1]heptane derivative. Synthesis of reduction products of cis-maneonene-A

Abstract

The addition of fumaryl chloride to furan, followed by hydrolysis and bromolactonisation of the adduct, leads to the bromo-lactone acid (2a) which serves as a precursor for the synthesis of the reduction products (5a), (5b), and (6a) of cis-maneonene-A and of the tosylate (6b) whose X-ray crystal structure has been determined.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 542-544

Diels–Alder reaction of furan and fumaryl chloride: X-ray crystal and molecular structure of an oxabicyclo[2.2.1]heptane derivative. Synthesis of reduction products of cis-maneonene-A

C. L. D. Jennings-White, A. B. Holmes and P. R. Raithby, J. Chem. Soc., Chem. Commun., 1979, 542 DOI: 10.1039/C39790000542

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