The known bis(silyloxy)bicycloheptanone (1) has been converted into prostaglandin-E2(7) in seven steps, and the readily prepared mono-protected dihydroxyketone (10) has been photoisomerised to the known prostaglandin-C2 precursor (11).
N. M. Crossland, S. M. Roberts, R. F. Newton and C. F. Webb, J. Chem. Soc., Chem. Commun., 1978, 660 DOI: 10.1039/C39780000660
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