Issue 5, 1975

14N–31P, 15N–15P, and 31P–31P coupling constants from the 31P nuclear magnetic resonance spectra of square planar platinum(II) and palladium(II) thiocyanate complexes

Abstract

The 31P n.m.r. spectra of cis-PtX2[P(OPh)3]2(X = CNS, C15NS) show the independent existence of dithiocyanato, diisothiocyanato and mixed linkage isomers in solution, and the appearance of distinct resolvable 31P–31P, 14N–31P and 15N–31P coupling in the spectra of the mixed species suggests a means of measuring these couplings in co-ordination complexes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 175-176

14 N–31P, 15N–15P, and 31P–31P coupling constants from the 31P nuclear magnetic resonance spectra of square planar platinum(II) and palladium(II) thiocyanate complexes

A. J. Carty and S. E. Jacobson, J. Chem. Soc., Chem. Commun., 1975, 175 DOI: 10.1039/C39750000175

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