SCHEDULED MAINTENANCE
The orange liquid B4H8Fe(CO)3 has been prepared by direct reaction of pentaborane(9) with iron pentacarbonyl and also by the reaction of tetraborane(10) with enneacarbonyldi-iron; spectroscopic evidence shows that the Fe(CO)3 group has replaced the apex BH group in B5H9 and that the compound has structural and bonding affinities with C4H4Fe(CO)3 and C[Fe(CO)3]5.
N. N. Greenwood, C. G. Savory, R. N. Grimes, L. G. Sneddon, A. Davison and S. S. Wreford, J. Chem. Soc., Chem. Commun., 1974, 718 DOI: 10.1039/C39740000718
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