Issue 10, 1974

Stereospecific synthesis of the trans-anti-trans- and trans-syn-trans- isomers of dicyclohexyl-18-crown-6

Abstract

The macrocyclic polyethers, (7) and (8), have been synthesised stereospecifically from the diastereoisomeric acyclic methylene acetals, (1) and (2), obtained from (±)-cyclohexane-trans-1,2-diol; both (7) and (8) form stable complexes with metal cations.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 390-391

Stereospecific synthesis of the trans-anti-trans- and trans-syn-trans- isomers of dicyclohexyl-18-crown-6

J. F. Stoddart and C. M. Wheatley, J. Chem. Soc., Chem. Commun., 1974, 390 DOI: 10.1039/C39740000390

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