Dismutation of two different electron-rich olefins C2X4 and C2Y4 proceeds only in the presence of an additive, compounds such as L(Ph3P)2RhCl (L = Ph3P or CO) being particularly effective; carbene complexes L(Ph3P)Rh(CX2)Cl and L(Ph3P)Rh(CY2)Cl are isolable intermediates and the active catalysts.
D. J. Cardin, M. J. Doyle and M. F. Lappert, J. Chem. Soc., Chem. Commun., 1972, 927 DOI: 10.1039/C39720000927
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