Long range structural and textural changes in [Zn(bdc)(ted)0.5] upon spontaneous dispersion of LiCl and hysteretic adsorption and desorption of carbon dioxide and hydrogen†
Abstract
A LiCl containing Zn(bdc)(ted)0.5 metal–organic framework (MOF) was prepared via an innocuous impregnation and thermal spontaneous dispersion process. The dispersion of the LiCl and crystallinity of the modified microporous framework were verified via standard and in situ