Issue 14, 2012
From the journal:

Organic & Biomolecular Chemistry

A novel ketone olefination via organozinc reagents in the presence of diphenyl phosphite†

Hua Cui,a   Ying Lia  and  Songlin Zhang*a  

* Corresponding authors

a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science of Soochow University, Suzhou 215123, People's Republic of China
E-mail: zhangsl@suda.edu.cn

Abstract

Carbonyl compounds react with organozinc reagents in the presence of diphenyl phosphite to give the corresponding olefins. A variety of 1,3-dienes and unsaturated esters were obtained in moderate to excellent yields under mild conditions.

Graphical abstract: A novel ketone olefination via organozinc reagents in the presence of diphenyl phosphite

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Article information

DOI
https://doi.org/10.1039/C2OB06821D
Article type
Paper
Submitted
31 Oct 2011
Accepted
12 Jan 2012
First published
13 Jan 2012

Org. Biomol. Chem., 2012,10, 2862-2869

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A novel ketone olefination via organozinc reagents in the presence of diphenyl phosphite

H. Cui, Y. Li and S. Zhang, Org. Biomol. Chem., 2012, 10, 2862 DOI: 10.1039/C2OB06821D

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