Issue 11, 2013

A 24-Gd nanocapsule with a large magnetocaloric effect

Abstract

Two 24-nuclear lanthanide clusters, Gd24 and Dy24 were obtained and structurally characterized. Magnetic investigations reveal that Gd24 exhibits the largest entropy change (−ΔSm) of 46.12 J kg−1 K−1 for ΔH = 7 T in all reported molecular clusters, and single-molecule magnet behaviour is observed in Dy24.

Graphical abstract: A 24-Gd nanocapsule with a large magnetocaloric effect

Supplementary files

Article information

Article type
Communication
Submitted
10 Aug 2012
Accepted
29 Oct 2012
First published
29 Oct 2012

Chem. Commun., 2013,49, 1055-1057

A 24-Gd nanocapsule with a large magnetocaloric effect

L. Chang, G. Xiong, L. Wang, P. Cheng and B. Zhao, Chem. Commun., 2013, 49, 1055 DOI: 10.1039/C2CC35800J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements