Permethylated linear polysilanes Me[SiMe2]nMe (n= 3–6) and branched-chain polysilanes Me3Si[(Me3Si)SiMe]nSiMe3(n= 1,2) undergo photolysis at room temperature with loss of dimethylsilylene Me2Si: in the former case and (trimethylsilyl)methylsilylene Me3SiSiMe: in the latter.
M. Ishikawa and M. Kumada, J. Chem. Soc. D, 1971, 489 DOI: 10.1039/C29710000489
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