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A combination of evidence from isolations and from tracer experiments supports the sequence (1)→(7) and (9)⇄(11) and (13)(and similarly for the methoxylated series) as the pathway to the Cinchona alkaloids: the results also point to cinchonaminal (3) as being the key intermediate between (1) and (7).
A. R. Battersby and R. J. Parry, J. Chem. Soc. D, 1971, 31 DOI: 10.1039/C29710000031
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